The earliest use he has found is by Arnold Sommerfeld in Annalen der Physik
around 1916 or 1917. He says the symbol was not used by Gibbs in Vector
Analysis (around 1896) and was not used by E. B. Wilson in Advanced Calculus
(1911), although Wilson used an integral symbol with a circle beneath it
(where the C appears now).
The symbol is not mentioned by Cajori.
Thanks in advance!
Jeff Miller
http://members.aol.com/jeff570/mathsym.html